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Technical guide Tecalemit Flexibles®

The range of TECALEMIT FLEXIBLES® technical tubes are divided into 8 families. First the monocomponent tubes :
- MANURIL® polyamide tubes
- MANULAN® polyurethane tubes
- PTFE TECAFLON® PTFE tubes
- PVDF MANULEF® PVDF tubes
- MANULENE® low-density polyethylene tubes
The range is enriched by the following tubes of composite structure :
- MANUCLAIR® PVC tubes (pvc tube/textile braid/pvc cover)
- MANUFLEX® tubes (nitrile rubber tube/galvanised steel braid/pvc cover) - MALUFORM® (aluminium tube/polyethylene
cover)
Production of tubes :
Mono-component tubes are produced by extrusion, whose parameters vary according to material and diameters, but which practically all have the following stages, wiith the exception of ptfe which is produced by vertical ram extrusion.
First the granules of these thermoplastic materials are brought to their melting temperature, homogenised and compressed by the
helical screw of the extruder.
Passing through the extrusion head, the liquid plastic material is projected towards a cooled calibrated die, under vacuum,
accompanied by a film of water. The tube is then cooled, and its wall thickness controlled by ultra-sound and its outer diameter
controlled by infra-red.
These control figures are used to fine-tune the parameters of the extruder with regards to outer diameter and wall thickness. The
surface of the tube is then passed through a flame before being ink marked by thermo-diffusion, befor arriving at the final traction devices for winding on reels.

Technical generalities of mono-component tubes

Institutes of standards define a certain number of characteristics of polyamide and polyurethane tubes in general use or used for vehicle brake systems. They particularly cover inner and outer dimensions and thicknesses that can be found in the technical characteristics table of MANURIL® and MANULAN® tubes. They also cover working and burst pressures which are also indicated.
These standards also define a certain number of tests which characterise the aptitude of the tube’s use.
For instance :
- Tests on the absorption of moisture checks dimensional stability in humid atmospheres
- Testing the resistance to zinc chlorate checks the aptitude of the tube when used in contact with metallic parts (fittings)
- Aging tests
- Cold flexibility tests
- Cold impact tests which, combined the previous test defines the minimum temperature for use.
Other tests can be defined which concern the quality of the the material and these tests can be found in the preceding paragraph .
One of these tests concerns the load tension :
The burst pressure of a tube is directly issued from the load on the material at a test temperature, according to following formula :

Pe = Tc x 20 x Ep / (De – Ep)

Where for a test temperature :
BP = Burst pressure in bars
LT = Load tension in n/mm2
TH = Thickness of tube in mm
OD = Outer diameter of tube in mm

Hereafter follows some values of the load tension at 23°C :
- Plastified polyamide (MANURIL® semi-rigid tube) : LT = 20 n/mm2
- Rigid polyamide (MANURIL® rigid tube)) : LT = 40 n/mm2
- Polyurethane (MANULAN® tube) : LT = 9 n/mm2
- Polyethylene (MANULENE® tube) : LT = 8 n/mm2

Comparison table of characteristics of different materials:
FAMILY POLYAMIDE POLYURETHANE FLUORINATED
POLYMERS
POLYETHYLENE VINYL ELASTOMERES
MATERIAL PA11PHL PA12PHL PA12 HL Polyether
Base
Base
Polyester
PTFE PVDF PEBD Flexible
PVC
NBR
Physical properties
Volumic mass (g/cm3) 01/05/18 01/03/18 01/02/18 01/01/15 01/01/21 01/02/17 01/01/78 0.91 01/01/38 0.95
Water absorption (%) 01/05/18 01/04/18 01/06/18 01/05/18   0.01 0.03 0.03   0.01
Moisture absorption (%) 0.7 0.6 0.7     0.01 0.015     0.01
Crystalinity (%) 25.0 25.0       85 50.0 65 0.0 72.0
Mechanical properties
Elasticity modulus (mpa)   430 1440 70 160 350 1700 300 1500 500
Yield strength (Mpa) 27 24 41 11 8 30 50 13 15 24
Elongation at yield (%) 32 25 8 50 50   7      
Breaking strength (Mpa) 48 50 53 56 60 25 48 18 17 25
Elongation at break (%) 300 290 310 490 480 250 51      
Elasticity modulus in flexion (mpa) 350 400 1200 500 550   2000 200 1500 1150
Creep modulus in traction 1 hour (Mpa)   800       750 1050      
Creep modulus in traction 1000 hours (Mpa)   450         570      
Charpy notch test (KJ/m2) 16 99 08/05/18 20     14     4
Choc Izod non entaillé (KJ/m2) 20 12       NB        
Izod un-notch test (KJ/m2) 07/04/18 4       16 10     01/03/00
Hardness shore A 99 99   96         70 65
Hardness shore D 62 60 70 48 50 58 77 43    
Resistance to abrasion       40 42 Faible        
Thermal properties
Melting temperature (°c) 182 174 178     327 170 11 80 135
Temp. of deflection under load 1.8 mpa (°C) 45 46 55 62 105 55 105 30   50
Temp. of deflection under load 0.45 mpa (°C) 130 125 135 100   135 135 40   85
Vicat b softening temperature (°C) 160 145 145 75 90 110 140 80    
Cold fragility temperature (°C)       -50 -40 -175 -40 -80 -20 -80
Thermal conductivity (wm-1k-1) 0.29 0.32 0.32 0.22 0.25 0.24 0.18 0.30 0.17 0.40
Flame properties
Flammability of a 1.6mm thick tube HB HB HB HB à V2   VO VO HB HB HB
Oxygen index (%) 25         95 44 17 30 17
Electrical properties
Dielectric constant 100khz   03/07/18 03/07/18 04/05/18   2 11   4 02/04/18
Dielectric constant 1mhz 03/07/18 02/02/18 02/02/18 04/02/18   2 8 02/03/18   02/04/18
Dissipation factor 100mhz       0.018   0.00003 0.025 0.0003 0.1 0.0003
Dissipation factor 1mhz 0.05 0.03 0.03 0.01   0.0005 0.23 0.0002   0.0004
Transverse resistivity (ohm) 7.8E+13 1.0E+15 1.0E+15 7.0E+14   1,00E+018 2.0E+14 1.0E+17 1.0E+13 1.0E+17
Superficial resistivity (ohm) 1.0E+14 1.0E+14 1.0E+14 1.0E+14   1.0E+15 1.0E+15 1.0E+15   1.5E+13
Dielectric rigidity (kv/mm) 23 24 32 25     27 40 20 17 à 120
Comparative tracking index       600   600 600 140   600
Arc resistance (dry)           200 60      
Optical properties
Transparency Poor Bad Bad Good Good Bad 93,00% Good Good Bad

Physical properties

- Definition of volumic mass :

The volumic mass is the mass by volume unit of a material at a given temperature (°C). It is expressed in Kg/m3 (or g/cm3).
Please note that volumic mass indicated in the comparison table of different materials is, of course, in their solid state as determined
by NF T 51-063.

- Absorption of water and moisture :

Absorption of water plays an important role with regards to electric properties, mechanical properties (for example, polyamides are plastified by water) and for long term properties for materials subject to hydraulic degradation.
The action of water can also give way to modifications in dimensions.
The following table gives water absorption values according to NF T 51-166 and moisture absorption values according
to NF T 51-290.

- Definition of transparency :

Transparency is the ability of a body to regularly transmit (without scattering) a beam of light.
It is expressed as a percentage according to standard NF T 51-068 or else according to an approximate criterion.

Mechanical properties

- Definition of elasticity modulus :

The elasticity modulus (or tensile modulus) is defined as the slope creating the tangent of the stress-strain curve in low
deformations.
Physically, this characteristic expresses the stiffness of the material (the higher the value, more the tube is rigid).
It is expressed in megapascals (Mpa) and obtained by tensile tests according to NF T 51-034

- Definition of yield stress :
Yield stress is usually employed as the the yield point. It is defined as the force applied to the yield stress point by the initial section of the sample on which a tensile load is applied according to NF T 51-034 and expressed in megapascals (Mpa).

- Definition of breaking stress :
Breaking stress is defined as the quotient of the applied force at the time when the sample breaks by its
initial section.
It is obtained by tensile tests according to NF T 51-034 and expressed in megapascals (Mpa).

- Definition of elasticity in flexion :
The elasticity modulus in flexion or flexion modulus or resistance to flexion qualifies the material’s resistance to deformation.
This value is determined by a flexion test according to NF T 51-104 and expressed in megapascals (Mpa).

- Definition of creeping modulus :
Creeping is defined as a slow deformation of a solid subjected to sufficiently prolonged efforts.
Under this constant force, the solid is subjected to a primary deformation during application of the effort and it is only from this point that any deformation is due to creeping.
It is expressed in megapascals and determined by NF T 51-103 and given for 1 hour and 1000 hours.

- Impact behaviour :
The values obtained during tests allow an estimation, in experimental conditions, of the fragility of a material.
The table gives results according to the Charpy test (widely used in Europe and given according to NF T 51-035) and the IZOD test (used in the United States and given according to NF T 51-035) and for notched and un-notched samples.

- Definition of hardness :
The shore hardness given in the table is according to NFT 51-109 and obtained by using simple conical indenters with direct reading from 0 to 100 (‘0’ corresponds to full penetration, ‘100’ corresponding to maximum hardness, that is no penetration of the indenter into the material).
Two scales of hardness are used : shore A for soft materials and shore D for harder ones.
The difference in readings comes simply from the shape of the indenter.

- Definition of resistance to friction :
Wear is a loss of material from the surface of a body subjected to a mechanical action and is always due to the contact of the material with a foreign body.
In the case of tubes, it can be the rubbing against a solid body, contact with an abrasive element or contact with a point,
creating a scratch.
Wear is measured in mm2 (of surface worn during test) or in mm3 (volume of material recuperated following friction test) as well as the tangential force resulting from friction and the normal force applied on the sled used for testing.

Thermal properties

- Definition of melting and crystallisation temperatures :

Melting temperature is the moment when the material passes from a crystallised state to a liquid state.
Crystallisation temperature is when the material passes from a liquid state to a crystalised state.
Many methods (often visual) are used to obtain these values according to the material : these have been used to
complete the following table.
The melting temperature of plastics only has meaning if the material has a definite melting point at a determined temperature.
In the other case, it is preferable to consider the Vicat softening temperature described hereafter.

- Definition of temperature of deflection under load :
Temperatures of deflection under different load values characterise the behaviour of rigid plastics under load at high temperatures.
This value is particularly important in the case of tubes as it indicates the reduction of supported pressures under the effect of a hot liquid.
They are given in degrees celsius according to NF T 51-005 which describes, for example, the increase rate of temperature : This way, normalised values can be distanced from the real use of the tube and it is for this reason that individual tube data sheets give the reductions in working pressures according to working temperature.

- Definition of Vicat softening temperature :
The temperature at which a flat-ended rod of 1mm2 penetrates a sample is considered the Vicat softening temperature.
It largely replaces the melting temperature in the case where the material does not have a definite melting point at a
determined temperature.
This value is given in degrees celsius according to normalised test NF T 51-021.

- Definition of temperature of cold brittleness :
It is a conventional temperature at which flexible plastic materials at ambient temperature, present brittle fracture according to the mechanical tests described above in the impact behaviour of materials (Charpy or Izod tests).
They can also be determined by a torsion test according to NF T 51-104.
It can be used for specifications or to compare different tubes, but does not necessarily determine the lowest temperature at which the tube can be used.

- Definition of thermal conductivity :
Conductivity quantifies the capacity of a material to conduct heat. The indicated values correspond to the normalised test
NF X 10-021 and are expressed in watts per metre and per degree kelvin (W.m-1.K-1).

Flammability properties

- Definition of UL94 flammability :
The widely used UL94 flammability test has, for object, to indicate the capacity of a material to allow a flame to extinguish itself, once lit.
The best classification is VO followed, in order, by V1, V2z and lastly HB. It is important to note that UL 94 classification must always indicate the thickness of the sample used.
Whereby, the same material can be classed VO in 1.6mm thickness and V1 in 3.2mm thickness.
Certain materials are naturally fire-resistant (for example PTFE), for the other polymers, it is possible to increase their flame resistance with fire-resistant additives.

- Definition of oxygen rating :
The oxygen rating according to NF T 51-071 gives an idea of the material’s behaviour under combustion by indicating the minimum percentage of oxygen in an oxygen-nitrogen mixture which maintains the material in combustion.
The higher this value, the better the behaviour of the material under flame.

Chemical compatibility chart

This guide has been designed to assist in the optimal choice of the material comprising TECALEMIT FLEXIBLES® technical tubes, according to conveyed or surrounding fluids.
The following information results from static tests on solid samples immersed in chemical reactives (or their dilutions)
Not taken into account :
- Dynamic reaction, particularly cracking under strain
- Synergy effects when several fluids are in contact
Miscellaneous external aggressions should also be taken into account : Weather - ultraviolet - temperature - pressure, etc... to which tubes can be subjected.
The chemical products listed are the most frequently encountered ones.
Please contact the technical department for any particular assistance.

Abbreviations :
TEMP °C : Temperature expressed in degrees CELSIUS
P.A : Polyamide 12 - MANURIL®
P.U : Polyurethane - MANULAN®
P.E : Polyethylene - MANULÈNE®
P.V.D.F : Polyvinylidene fluoride - MANULEF®
F.E.P : Fluorinated ethylene propylene
P.F.A : Perfluoralkoxy
P.T.F.E : Polytetrafluoroethylene
P.V.C : Polyvinyl chloride
N.B.R : Nitrile butadiene rubber

download the table of chemical resistance


icone pdf

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